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An Ion-Selective Electrode for Ethylenediaminetetraacetatobismuthate(III) Anions
Authors:S. V. Kharitonov  N. B. Minevich  I. P. Gorelov
Affiliation:(1) Tver State University, Sadovyi per. 35, Tver, 170002, Russia
Abstract:The main characteristics of liquid-membrane ion-selective electrodes (ISEs) based on high-molecular quaternary ammonium salts (QASs) were studied. The electrodes are reversible to the ethylenediaminetetraacetatobismuthate(III) anion. It was found that the selectivity of the ISEs to the potential-determining ion depends on the symmetry of the QAS. A mechanism of the ISE membrane response was proposed.
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