An Ion-Selective Electrode for Ethylenediaminetetraacetatobismuthate(III) Anions |
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Authors: | S. V. Kharitonov N. B. Minevich I. P. Gorelov |
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Affiliation: | (1) Tver State University, Sadovyi per. 35, Tver, 170002, Russia |
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Abstract: | The main characteristics of liquid-membrane ion-selective electrodes (ISEs) based on high-molecular quaternary ammonium salts (QASs) were studied. The electrodes are reversible to the ethylenediaminetetraacetatobismuthate(III) anion. It was found that the selectivity of the ISEs to the potential-determining ion depends on the symmetry of the QAS. A mechanism of the ISE membrane response was proposed. |
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