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Optical resolution of racemic 4-hydroxy-3-isobornyl-5-methylbenzaldehyde
Authors:E.?V.?Buravlev  author-information"  >  author-information__contact u-icon-before"  >  mailto:buravlev-ev@chemi.komisc.ru"   title="  buravlev-ev@chemi.komisc.ru"   itemprop="  email"   data-track="  click"   data-track-action="  Email author"   data-track-label="  "  >Email author,I.?Yu.?Chukicheva,A.?V.?Churakov,A.?V.?Kutchin
Affiliation:1.Institute of Chemistry, Komi Research Center, Ural Division,Russian Academy of Sciences,Syktyvkar,Russia;2.Kurnakov Institute of General and Inorganic Chemistry,Russian Academy of Sciences,Moscow,Russia
Abstract:Racemic 4-hydroxy-3-isobornyl-5-methylbenzaldehyde was separated into particular enantiomers via transformation into diastereoisomeric Schiff bases by reaction with (R)-1-phenylethanamine. The absolute configuration of the products was determined on the basis of the X-ray diffraction data for camphanate derived from one enantiomer of 4-hydroxy-3-isobornyl-5-methylbenzaldehyde.
Keywords:
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