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Homodimeric coupling-cyclization reaction of 2,3-allenamides
Authors:Guofei Chen
Institution:Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, 310027 Hangzhou, Zhejiang, PR China
Abstract:The PdCl2/NaI/K2CO3-catalyzed highly stereoselective homodimeric coupling-cyclization reaction of 2,3-allenamides afforded Z-bis(furanimine) derivatives. The addition of K2CO3 is crucial for this reaction and a possible mechanism is proposed.
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