Homodimeric coupling-cyclization reaction of 2,3-allenamides |
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Authors: | Guofei Chen |
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Institution: | Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, 310027 Hangzhou, Zhejiang, PR China |
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Abstract: | The PdCl2/NaI/K2CO3-catalyzed highly stereoselective homodimeric coupling-cyclization reaction of 2,3-allenamides afforded Z-bis(furanimine) derivatives. The addition of K2CO3 is crucial for this reaction and a possible mechanism is proposed. |
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