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Cycloaddition of allylsilanes. Part 20: Organosilicon-mediated total synthesis of (±)-cameroonanol |
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| Authors: | Arndt W Schmidt |
| Institution: | Department Chemie, Technische Universität Dresden, Bergstraße 66, 01069 Dresden, Germany |
| Abstract: | We describe a seven-step total synthesis of the triquinane sesquiterpene (±)-cameroonanol using a Lewis acid-promoted 3+2] cycloaddition of an allylsilane and a modified Fleming-Tamao oxidation as key reactions. |
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