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| THE SYNTHESIS AND CHARACTERIZATION OF ANSYMMETRIC PENTAAZADENTATE PORPHYRIN-LIKE METAL COMPLEXES | |
| 摘 要： | This paper presents the synthesis and structural characterization of asymmetrictripyrrane-containing macrocycle.This macrocycle could be oxidized to the methinebridged,22 π-electron aromatic macrocyclic complexes containing cadmium(Ⅱ),samarium(Ⅲ),europium(Ⅲ)and gadolinium(Ⅲ)by treating with corresponding metal chloride inthe presence of air Their structures were characterized by spectral methods. |
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