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Thermochemical behavior of mixtures ofN,N-dimethylformamide with dimethylsulfoxide,acetonitrile, andN-methylformamide: Volumes and heat capacities
Authors:Cees de Visser  Gus Somsen
Institution:(1) Department of Chemistry, Free University, de Boelelaan 1083, Amsterdam, The Netherlands
Abstract:Densities and molar heat capacities have been measured for mixtures ofN,N-dimethylformamide with dimethylsulfoxide, acetonitrile, andN-methylformamide at 25°C over the complete mole fraction range. From these data the apparent molar volumes and heat capacities have been calculated for both components. These quantities, as a function of the mole fraction, deviate very little from their molar values, indicating that the mixtures can be regarded as almost ideal.
Keywords:Molar volume  density  molar heat capacity  N  N-dimethylformamide  dimethylsulfoxide  acetonitrile  N-methylformamide
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