Syntheses,crystal structures,and electrochemical properties of transition metal complexes with new tetrathiafulvalene-derivatized acetylacetonate ligands |
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| Authors: | Peng Zheng Yun-Jun Guo Wei Liu Yi-Zhi Li Jing-Lin Zuo Xiao-Zeng You |
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| Institution: | (1) Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, People’s Republic of China |
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| Abstract: | Two new tetrathiafulvalene (TTF) derivatives of acetylacetone, namely, 3-{6,7-benzo-2-(methylthio)-TTF-3-yl}-thio]-2,4-pentanedione
(L1) and 3-{6,7-(ethylenedithio)-2-(methylthio)-TTF-3-yl}-thio]-2,4-pentanedione (L2), have been synthesized. Four transition metal(II) complexes of these ligands, of general formulae Zn(L1)2(THF)2] and M(L2)2(THF)2] (M = Zn, Mn, and Ni), have been prepared and structurally characterized. The redox properties of both the ligands and their
complexes were investigated by cyclic voltammetry.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
Peng Zheng and Yun-Jun Guo contributed equally to this work. |
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