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A facile conversion of thio- and selenophosphoric acids and their derivatives into fluoridates by means of reaction with silver fluoride |
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| Authors: | Arkadiusz Chworo Lucyna A Wo niak |
| Institution: | aPolish Academy of Sciences, Centre of Molecular and Macromolecular Studies, Department of Bioorganic Chemistry, Sienkiewicza 112, 90-363 Łódź, Poland |
| Abstract: | Treatment of numerous thio- or selenophosphorus acids with aqueous silver fluoride in CHCl3 at room temperature results in clean formation of the corresponding fluoridates. Analogous results were obtained with other phosphorothio (seleno)ates such as esters, amidates, or halides. |
| Keywords: | Halogenation (Fluorination) Oxygenation Phosphorus compounds Thiophosphorus compounds |
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