Unravelling the reactivity of antisymmetric stretch-excited CH4 with Cl by-product pair-correlation measurements |
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| Authors: | Kawamata Hiroshi Tauro Sandeep Liu Kopin |
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| Institution: | Institute of Atom and Molecular Sciences, Academia Sinica, P. O. Box 23-166, Taipei, Taiwan 10617. |
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| Abstract: | The vibrational branching ratio CH(3)(v=0) + HCl(v'=1)]/CH(3)(v=0) + HCl(v'=0)] of two correlated product pairs from the title reaction shows a dramatic E(c)-dependence, in sharp contrast to the previously observed behavior in Cl + CHD(3)(v(1)=1), while the vibrational enhancement factors in reactivity of the two reactions are remarkably similar. |
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