摘 要: | The reaction between sodium trifluoromethanesulfinate, which was prepared from trifluorome-thyl bromide, with bromine in aqueous solution resulted in the formation of trifluoromethanesulfonylbromide (CF_3SO_2Br). CF_3SO_2Br reacted with alkenes and alkyne to give the corresponding adductswith the loss of SO_2 in good yields, and with compounds containing active hydrogen to give brominatedderivatives. A radical reaction mechanism was proposed and confirmed by EPR study.
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