| 毛细管柱气相色谱法测定人血清中有机氯农药残留量 |
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| 引用本文： | 王茜,李茂静,荣素英,钱庆增,李颖超,张峻,关维俊. 毛细管柱气相色谱法测定人血清中有机氯农药残留量[J]. 理化检验(化学分册), 2010, 0(4) |
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| 作者姓名： | 王茜 李茂静 荣素英 钱庆增 李颖超 张峻 关维俊 |
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| 作者单位： | 华北煤炭医学院预防医学系;河北省煤矿卫生与安全实验室;唐山市环保监测站;唐山市职业技术学院; |
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| 基金项目： | 唐山市科学技术研究与发展计划课题(07130206A-4-6) |
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| 摘 要： | 提出了毛细管气相色谱测定人血清中有机氯农药残留量的方法。利用正己烷超声提取人血清样品中有机氯农药六六六和滴滴涕,所得萃取液作气相色谱测定,用甲酸及浓硫酸净化、磺化处理后,电子捕获检测器检测。在优化的试验条件下,8种有机氯农药同分异构化合物组分在20 min内能够很好的分离,其质量浓度与色谱峰面积在0.4～10μg·L~(-1)浓度范围内呈线性关系,检出限(3S/N)在0.07～0.30μg·L~(-1)之间。方法的日内的相对标准偏差为2.9%～5.4%,日间的相对标准偏差为4.5%～8.9%。方法的加标回收率在81.5%～117.6%范围。
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| 关 键 词： | 气相色谱法 毛细管柱 人血清 有机氯农药残留 |
GC Determination of Residual Amounts of Organochlorine Pesticides in Human Serums with Capillary Chromatographic Column |
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| WANG Qian,LI Mao-jing,RONG Su-ying,QIAN Qing-zeng,LI Ying-chao,ZHANG Jun,GUAN Wei-jun. GC Determination of Residual Amounts of Organochlorine Pesticides in Human Serums with Capillary Chromatographic Column[J]. Physical Testing and Chemical Analysis Part B:Chemical Analgsis, 2010, 0(4) |
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| Authors: | WANG Qian LI Mao-jing RONG Su-ying QIAN Qing-zeng LI Ying-chao ZHANG Jun GUAN Wei-jun |
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| Affiliation: | 1/a>;2;1/a>;2;1.Dept.of Preventive Medicine/a>;North China Medical College of Coal Industry/a>;Tangshan 063000/a>;China/a>;2.Hebei Provincial Lab.of Labour Hygiene and Safety of Coal Mining/a>;3.Tangshan Municipal Environmental Monitoring Station/a>;4.Tangshan Techno-vocational College/a>;China |
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| Abstract: | Gas chromatography with capillary column was applieed to the determination of residual amounts of organochlorine pesticides in human serum.The sample was diluted with formic acid and extracted with n-hexane ultrasonically.The upper organic layer was taken and sulfonated with conc.H_2 SO_4.The sulfonated solution layer was separated and evaporated to near dryness in a vacuum dryer.The residue was taken up with 1 mL of n-hexane and used for GC analysis,with electron capture detector.Four isomers each of the p... |
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| Keywords: | Gas chromatography Capillary column Orgaochlorine pesticide residues Human serum |
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