| 具有纳米尺寸的四聚四硫富瓦烯大环冠醚的合成 |
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| 引用本文： | 尹炳柱,温全武,陈铁,刘武军,丛志奇,金龙一,和田猛,西乡和彦. 具有纳米尺寸的四聚四硫富瓦烯大环冠醚的合成[J]. 有机化学, 2005, 25(2): 188-192 |
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| 作者姓名： | 尹炳柱 温全武 陈铁 刘武军 丛志奇 金龙一 和田猛 西乡和彦 |
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| 作者单位： | 1. 延边大学理工学院化学系,延吉,133002
2. 东京大学大学院新领域创成科学研究科,东京,日本,113-8656 |
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| 摘 要： | 以二(碘乙基)醚和2,3-二氰乙硫基四硫富瓦烯衍生物作为起始原料, 采用腈乙基保护与脱保护技术, 通过多步反应以较好的收率合成了两个纳米结构的大环四硫富瓦烯冠醚5a～5b. 通过循环伏安法(CV)研究了化合物4b和5b的电化学性质, 并用1H NMR谱研究了5b与[60]富勒烯之间的相互作用. 结果表明: 5b存在环结构效应, 与[60]富勒烯有一定程度的电荷转移相互作用.
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| 关 键 词： | 四聚四硫富瓦烯36-冠-12 电荷转移络合作用 环结构效应 |
| 收稿时间： | 2004-02-23 |
| 修稿时间： | 2004-02-23 |
Synthesis of Nanoscale Octathia 36-Crown-12 Annu-latedTetrathiafulvalene Tetramers |
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| YIN,Bing-Zhu,a WEN,Quan-Wua CHEN,Tiea LIU,Wu-Juna CONG,Zhi-Qia JIN,Long-Yia WADA,Takeshib SAIGO,Kazuhikob. Synthesis of Nanoscale Octathia 36-Crown-12 Annu-latedTetrathiafulvalene Tetramers[J]. Chinese Journal of Organic Chemistry, 2005, 25(2): 188-192 |
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| Authors: | YIN Bing-Zhu a WEN Quan-Wua CHEN Tiea LIU Wu-Juna CONG Zhi-Qia JIN Long-Yia WADA Takeshib SAIGO Kazuhikob |
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| Affiliation: | YIN,Bing-Zhu*,a WEN,Quan-Wua CHEN,Tiea LIU,Wu-Juna CONG,Zhi-Qia JIN,Long-Yia WADA,Takeshib SAIGO,Kazuhikob |
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| Abstract: | Two nanoscale crown ether annulated tetrathiafulvalene (TTF) tetramers 5a～5b were synthesized via several steps using bis(2-iodoethyl)ether and 2,3-biscyanoethyl TTF derivatives as starting materials by cyanoethyl protection/deprotection method. The electrochemical properties and charge-transfer (CT) interaction with [60]fullerene of open chain TTF tetramer 4b and the above mentioned macrocyclic compound 5b were studied by means of cyclic voltammetry (CV) and 1H NMR spectroscopy, and 5b showed macrocyclic effect and the considerable charge-transfer interaction with [60]fullerene. |
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| Keywords: | crown-12 anuulated TTF tetramer charge-transfer interaction macrocyclic effect |
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