Cleavage of P-S bonds and oxygenation by a trinuclear iron carboxylate: synthesis and structures of iron clusters containing group 15/16 anions |
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| Authors: | Mitkina Tatiana V Lan Yanhua Mereacre Valeriu Shi Weifeng Powell Annie K Rothenberger Alexander |
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| Institution: | Institut für Anorganische Chemie der Universit?t Karlsruhe, Geb. 30.45, Engesserstr. 15a, 76131, Karlsruhe, Germany. |
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| Abstract: | The first reactions of the trinuclear oxygen-centred iron carboxylate Fe(3)(mu(3)-O)(mu(2)-piv)(6)(H(2)O)(3)](piv) (piv=(t)BuCOO(-)) with the neutral ligand precursor RP(S)(mu-S)](2) (R=4-anisyl) are reported. |
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