Relationship between torsional frequency and potential barrier height forAB n type molecular system |
| |
| Authors: | Y S Jain B Singh B N Khanna |
| |
| Affiliation: | (1) Department of Physics, North-Eastern Hill University, 793 003 Shillong, India;(2) Department of Physics, Aligarh Muslim University, 202 001 Aligarh, India;(3) Present address: Oil and Natural Gas Commission, 785 685 Nazira, India |
| |
| Abstract: | A relationship between the torsional frequency (v 10) and the potential barrier (V n) has been determined forAB n type molecular system havingn-fold symmetry axis. It is found thatv 10 varies prominently asV n 1/2 ,V n andV n 2 in certain ranges. TheV n value computed fromv 10 andI* r has been compared with that obtained from other experimental data for someAB n units in different molecular-crystalline systems. Although there is in general a good agreement, in some cases the values differ significantly, perhaps due to the erroneous assignment of torsional mode and/or the large errors in theV n value obtained from other experimental data. |
| |
| Keywords: | Torsional frequency barrier height potential barrier |
| 本文献已被 SpringerLink 等数据库收录！ |
|
