Electrophoretic studies on the mixed nitrilotriacetate-penicillamine complexes of Pb2+ and UO
2
2+ |
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Authors: | B B Tewari |
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Institution: | (1) Department of Chemistry, Florida Institute of Technology, Melbourne, Florida 32901, USA |
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Abstract: | A technique involving the use of paper electrophoresis is described for the study of binary and mixed-complex systems in solution.
This technique is based on the movement of a spot of metal ion in an electric field with the complexants added in the background
electrolyte at pH 8.5. The concentration of primary ligand (nitrilotriacetate) was kept constant, while that secondary ligand
(penicillamine) was varied. A graph of logpenicillamine] versus mobility was used to obtain information on the mixed complexes
and to calculate stability constants. The stability constants of mixed-ligand complexes lead(II)-nitrilotriacetate-penicillamine
and uranyl(II)-nitrilotriacetate-penicillamine have been found to be 5.68 ± 0.09 and 6.56 ± 0.05 (logarithm stability constant
values), respectively, at ionic strength 0.1 M and a temperature of 35°C.
The text was submitted by the author in English. |
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