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Homo Diels-Alder chemistry in the synthesis of portulal: construction of the functionalized hydroazulene core
Authors:Bin Ma
Affiliation:Department of Chemistry, Boston University, 590 Commonwealth Ave., Boston, MA 02215, USA
Abstract:A highly stereoselective synthesis of the functionalized hydroazulene skeleton of portulal (1), has been achieved using the newly developed cobalt catalyzed [4+2+2] homo Diels-Alder chemistry.
Keywords:Homo Diels-Alder   Portulal   Hydroazulene
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