Solvent effects in a carbenoid N-H insertion route to triarylamines via 2-diazo-1,3-cyclohexanedione |
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| Authors: | Peter Livant |
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| Institution: | Department of Chemistry and Biochemistry, Auburn University, Auburn, AL 36849-5312, USA |
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| Abstract: | The Rh-carbenoid derived from 2-diazo-1,3-cyclohexanedione inserts into the N-H bond of arylalkylamines and diarylamines. A solvent for this reactive carbenoid is suggested. The insertion products undergo a Pd-mediated aromatization to afford alkyldiarylamines and triarylamines. |
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| Keywords: | Triarylamines Rhodium carbenoid N-H insertion Aromatization Rh2(OAc)4 Pd(CH3CN)2Cl2 Solvent effect |
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