Regioselective preparation of 5-amino- and 6-amino-1,3-benzoxazole-4,7-diones from symmetrical diaminophenol and aminoresorcinol |
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Authors: | Laetitia Bré hu |
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Affiliation: | Ipsen Research Laboratories, Institut Henri Beaufour, 5 avenue du Canada, 91960 Les Ulis, France |
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Abstract: | Regioisomeric 5-amino- and 6-amino- 1,3-benzoxazole-4,7-diones were prepared from 2,6-diamino-4-methoxyphenol and 2-amino-5-methoxyresorcinol, respectively. These symmetrical precursors have the property to be antisymmetrical to each other with respect to their amino and hydroxy substituents. |
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Keywords: | Benzoxazole Quinone Regioselectivity Symmetry Antisymmetry |
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