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Regioselective preparation of 5-amino- and 6-amino-1,3-benzoxazole-4,7-diones from symmetrical diaminophenol and aminoresorcinol
Authors:Laetitia Bré  hu
Affiliation:Ipsen Research Laboratories, Institut Henri Beaufour, 5 avenue du Canada, 91960 Les Ulis, France
Abstract:Regioisomeric 5-amino- and 6-amino- 1,3-benzoxazole-4,7-diones were prepared from 2,6-diamino-4-methoxyphenol and 2-amino-5-methoxyresorcinol, respectively. These symmetrical precursors have the property to be antisymmetrical to each other with respect to their amino and hydroxy substituents.
Keywords:Benzoxazole   Quinone   Regioselectivity   Symmetry   Antisymmetry
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