SnCl4-promoted rearrangement of 2,3-epoxy alcohol derivatives: stereochemical control of the reaction |
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| Authors: | Yasuyuki Kita Satoshi Matsuda Ryoko Inoguchi Jnaneshwara K. Ganesh Hiromichi Fujioka |
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| Affiliation: | Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka 565-0871, Japan |
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| Abstract: | The SnCl4-promoted rearrangement of 2,2,3,3-tetrasubstituted-2,3-epoxy-1-alcohol derivatives proceeded in a regio- and stereo-controlled manner to selectively give two types of rearranged products from a single isomer by changing the protecting group of the alcohol. |
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| Keywords: | SnCl4-promoted rearrangement Tetrasubstituted-2,3-epoxy alcohol Stereocontrol α-Alkoxy ketone β-Hydroxy ketone |
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