Novel method for catalyst immobilization using an ionic polymer: a case study using recyclable ytterbium triflate |
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Authors: | Byoung Se Lee |
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Institution: | Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA |
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Abstract: | A series of ionic polymers prepared by quarternization of cross-linked poly(4-vinylpyridine/styrene) (P/S) resins with several alkylating agents, including short-length PEG mesylate were used as polymeric supports to immobilize Yb(OTf)3. The efficacy of the polymer-bound catalyst was examined in a Mannich-type reaction. |
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Keywords: | Ionic polymer Catalyst immobilization ytterbium triflate |
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