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The multicomponent reaction of dimethoxycarbene, dimethyl butynedioate and electrophilic styrenes: an unprecedented synthesis of highly substituted cyclopentenone acetals
Authors:Vijay Nair  P.B. Beneesh  V. Sreekumar  S. Bindu  Rajeev S. Menon  Ani Deepthi
Affiliation:Organic Chemistry Division, Regional Research Laboratory, Trivandrum 695 019, India
Abstract:The zwitterionic species generated by the addition of dimethoxycarbene to dimethyl butynedioate is trapped by arylidenemalononitrile to yield cyclopentenone derivatives.
Keywords:Multicomponent reactions   Dimethoxycarbene   Zwitterions   Cyclopentenones
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