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Preparation and applications of a novel bis(tributylstannyl)cyclopropane: a synthetic equivalent of a cyclopropane-1,2-dianion
Authors:Nicolas Heureux
Affiliation:Université catholique de Louvain, Département de Chimie, Bâtiment Lavoisier Place Louis Pasteur 1, 1348 Louvain-la-Neuve, Belgium
Abstract:The preparation of the novel trans-1,2-bis-stannylcyclopropane 4 is described. Its applications in Kosugi-Migita-Stille cross-coupling and in tin-lithium exchange reactions are presented and discussed.
Keywords:Small ring systems   Tributyltin   Cyclopropanation   Cross-coupling   Lithiation
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