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Samarium/N-bromosuccinimide-induced reductive dimerization of carbonyl compounds
Authors:Bimal K Banik  Indrani Banik  Rogelio Cuellar
Institution:a Department of Chemistry, The University of Texas-Pan American, 1201 West University Drive, Edinburg, TX 78541, United States
b The University of Texas, M. D. Anderson Cancer Center, United States
Abstract:Stereoselective reductive coupling of carbonyl compounds has been achieved using samarium/N-bromosuccinimide in methanol. The combination of these agents has proved a powerful addition to the arsenal of samarium-based reductants currently utilized.
Keywords:Samarium  N-Bromosuccinimide  Reductive coupling  Electron transfer
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