Chiral ferrocenyl diphosphines for asymmetric transfer hydrogenation of acetophenone |
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| Authors: | Jé rô me Cabou |
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| Affiliation: | Laboratoire de Catalyse de Lille, Catalyse Asymétrique et Polymérisation, UMR CNRS 8010, ENSCL, 59 652 Villeneuve d’Ascq cedex, France |
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| Abstract: | The synthesis of new optically pure ferrocenyl diphosphines have been realized from (R)-(+)-N,N-dimethylaminoethylferrocene. Particularly, dissymmetric ferrocenyl diphosphines have been synthesized. The diphosphines have been used as ligands in asymmetric transfer hydrogenation of acetophenone in the presence of Ru catalysts. |
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| Keywords: | Diphosphines Ferrocene Transfer hydrogenation |
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