|
|||||
|
|
Intramolecular metathesis versus Kharasch reactions using the Grubbs metathesis catalyst: towards catalyst economy |
|
| Authors: | James Faulkner David Fengas Peter Quayle Stuart N Richards |
| Institution: | a School of Chemistry, The University of Manchester, Manchester M13 9PL, UK b Avecia, PO Box 42, Hexagon House, Blackley, Manchester M9 8ZS, UK c Medicinal Chemistry 1, GlaxoSmithKline Medicines Research Centre, Gunnels Wood Road, Stevenage, Herts. SG1 2NY, UK |
| Abstract: | The first generation Grubbs catalyst can promote either ring closing metathesis (RCM) or atom transfer radical cyclisation reactions (ATRC) depending upon the reaction conditions employed. |
| Keywords: | Grubbs Metathesis Kharasch Cyclisation Competition Decomposition Stability ATRC RCM |
| 本文献已被 ScienceDirect 等数据库收录！ | |