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1,3:4,6-Di-O-benzylidene-d-mannitol as a source for novel chiral intermediates through regioselective reductive cleavage
Authors:Appu Aravind
Institution:Department of Chemistry, Indian Institute of Technology-Madras, Chennai 600036, India
Abstract:Synthetically useful chiral intermediates have been synthesized starting from 1,3:4,6-di-O-benzylidene-d-mannitol by regioselective reductive cleavage using BF3·Et2O and Et3SiH in high yields.
Keywords:Regioselective  Reductive cleavage  Chiral intermediates  Chemoselective  Benzylidene acetals
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