1,3:4,6-Di-O-benzylidene-d-mannitol as a source for novel chiral intermediates through regioselective reductive cleavage |
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Authors: | Appu Aravind |
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Institution: | Department of Chemistry, Indian Institute of Technology-Madras, Chennai 600036, India |
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Abstract: | Synthetically useful chiral intermediates have been synthesized starting from 1,3:4,6-di-O-benzylidene-d-mannitol by regioselective reductive cleavage using BF3·Et2O and Et3SiH in high yields. |
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Keywords: | Regioselective Reductive cleavage Chiral intermediates Chemoselective Benzylidene acetals |
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