Aerobic oxidation of primary alcohols in the presence of activated secondary alcohols |
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| Authors: | Hiromichi Egami |
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| Institution: | Department of Chemistry, Faculty of Science, Graduate School, Kyushu University 33, CREST, Japan Science and Technology Agency (JST), Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan |
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| Abstract: | Chemoselective aerobic oxidation of primary alcohols in the presence of activated secondary alcohols was effected under irradiation of visible light by using (nitrosyl)Ru(salen) complex 6 that possesses bulky 1-ethyl-1-methylpropyl groups at C3, C3′, C5 and C5′, as catalyst. For example, oxidation of n-decanol was >50 times faster than oxidation of 1-phenylethanol at 10 °C. |
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| Keywords: | Ru(salen) complex Aerobic oxidation Oxygen Primary alcohol Aldehyde Photo-irradation |
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