A room temperature alternative of the Claisen rearrangement route to ortho allylated phenols: unique reactivity pattern of allylindium reagents |
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Authors: | Dipakranjan Mal Pallab Pahari Bidyut K Senapati |
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Institution: | Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India |
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Abstract: | Quinol ethers and quinone monoketals are shown to undergo formal anti-Michael addition reactions with allylindium reagents at room temperature to give only ortho allylated phenols in good yields. |
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Keywords: | Claisen rearrangement Quinol ethers Allylindium Anti-Michael |
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