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A convenient method for the preparation of primary amines using tritylamine
Authors:Vassiliki Theodorou  Valentine Ragoussis  Evangelos Zelepos  Maria Dimitriou
Institution:a Department of Chemistry, University of Ioannina, GR-451 10 Ioannina, Greece
b Department of Chemistry, Laboratory of Organic Chemistry, University of Athens, Panepistimiopolis, Zographou, GR-157 71 Athens, Greece
c Chemistry Laboratories, Agricultural University of Athens, Iera Odos, GR-118 55 Athens, Greece
Abstract:A simple method for the preparation of primary amines by treating N-tritylamines with trifluoroacetic acid has been established. The N-tritylamines were prepared by the reaction of alkyl halides or alkyl p-toluenesulfonates with tritylamine, or by the reaction of alkyl bromides with lithium tritylamide.
Keywords:Primary amines  Tritylamine  Tritylamide  Ammonia synthon  Amination  Aminating agent
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