Palladium mediated spiroketal synthesis: application to pheromone synthesis |
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| Authors: | Jeremy C. Conway Andrew C. Regan |
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| Affiliation: | a School of Chemistry, University of Manchester, Manchester M13 9PL, UK
b Syngenta, Jealott's Hill International Research Station, Bracknell, Berkshire RG42 6EY, UK |
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| Abstract: | Stereospecific Stille coupling reactions of 2-metallo-dihydropyrans with Z-vinyl iodo alcohols and subsequent cyclisation provides rapid access to 1,7-dioxaspiro[5.5]undecane family of spiroketals. |
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| Keywords: | Spiroketal Palladium Stille Vinyl iodide Stork Selenium |
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