Self-inclusion properties of C60-linked calix[5]arene |
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| Authors: | Takeharu Haino |
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| Institution: | Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan |
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| Abstract: | C60-linked calix5]arenes were synthesized and their intramolecular binding properties were investigated. The self-inclusion ratio of the C60 moiety was determined by using UV-vis spectroscopy, and the ratio depends on chain length, temperature, and solvent. Influence of temperature and solvent was explained by the thermodynamic data of the intramolecular complex formation process. |
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| Keywords: | Fullerene Calix[5]arene Self-inclusion Solvent effect Thermodynamic study |
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