A direct approach to α-hydroxy and α-chloro trifluoromethyl derivatives |
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| Authors: | Lucie Tournier |
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| Affiliation: | Laboratoire de Synthèse Organique associé au CNRS, Ecole Polytechnique, 91128 Palaiseau, France |
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| Abstract: | S-1-Acyloxy-2,2,2-trifluoroethyl and S-1-chloro-2,2,2-trifluoroethyl dithiocarbonates add efficiently to various functionalised olefins to give the corresponding adducts via a radical chain reaction initiated by a small amount of lauroyl peroxide. |
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| Keywords: | Trifluoromethyl Radical chain reaction Dithiocarbonate |
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