Polymer-bound diazonium salts for the synthesis of diazoacetic esters |
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| Authors: | Maarten Schroen |
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| Institution: | Institut für Organische Chemie, Universität Karlsruhe (TH), Fritz-Haber-Weg 6, D-76131 Karlsruhe, Germany |
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| Abstract: | Starting from Merrifield resin, various polymer-bound diazonium salts were prepared. Upon treatment with amino acid esters, resulting the appropriate triazenes, the corresponding diazoacetic esters were formed by basic cleavage. Scope and limitation of this transformation were investigated. |
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| Keywords: | Diazonium salts Diazoacetic esters Merrifield resin |
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