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Synthesis of (±)-cartorimine |
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| Authors: | Barry B Snider James F Grabowski |
| Institution: | Department of Chemistry MS 015, Brandeis University, Waltham, MA 02454-9110, USA |
| Abstract: | Heating pyranulose 4 and cinnamate 2 in the presence of 2,6-di-t-butylpyridine in CH3CN afforded the 5+2] cycloadduct, which was hydrolyzed to give 13% of cartorimine (1). |
| Keywords: | [5+2] Cycloaddition Oxypyrylium zwitterion Dipolarophile Pyranose |
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