Regioselective synthesis of triiodo-o-carboranes and tetraiodo-o-carborane |
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| Authors: | Hiroto Yamazaki |
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| Institution: | Faculty of Pharmaceutical Sciences, Tohoku Pharmaceutical University, 4-4-1, Komatsushima, Aoba-ku, Sendai 981-8558, Japan |
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| Abstract: | 3,6-Diiodo-o-carborane 3, 3,6,9-triiodo-o-carborane 5, 3,9,12-triiodo-o-carborane 6 and 3,6,9,12-tetraiodo-o-carborane 7, which are suitable building blocks for supramolecular assemblies and carboracycles, were regioselectively synthesized by means of electrophilic iodination and introduction of iodine atoms via reconstruction of the o-carborane cage. |
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| Keywords: | o-Carborane Regioselective iodination Supramolecules Macromolecules |
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