Synthesis of diaryl selenides using the in situ reagent SeCl2 |
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Authors: | Sanjio S. Zade,Harkesh B. Singh,Gotthelf Wolmershä user |
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Affiliation: | a Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India b Fachbereich Chemie, Universität Kaiserslautern, Postfach 3049, Kaiserslautern 67653, Germany |
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Abstract: | Reactions of in situ prepared SeCl2 with Grignard reagents (prepared from bromobenzene, o-tolyl bromide, 2,6-dimethyl-4-tert-butyl-1-bromobenzene, and 1-bromo-2-methylnaphthalene) and dilithiated benzamides (prepared from N-phenyl, N-cyclohexyl, and N-isopropyl benzamide) are described. |
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Keywords: | Selenium dichloride 2-Phenyl-1,2-benzisoselenazol-3(2H)-one Lithiation Diorganoselenide Benzamide |
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