The first total synthesis of trichostatin D |
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| Authors: | Seijiro Hosokawa Takashi Ogura |
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| Institution: | Department of Applied Chemistry, School of Science and Engineering, Waseda University, 3-4-1 Ohkubo, Shinjuku-ku, Tokyo 169-8555, Japan |
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| Abstract: | Trichostatin D and 6-epi-trichostatin D have been stereoselectively synthesized through a remote stereoinduction with a chiral vinylketene silyl N,O-acetal and glycosylation of hydroxyimide under Mitsunobu conditions. |
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| Keywords: | Total synthesis Trichostatin D Vinylketene silyl N O-acetal Glycosylation |
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