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Synthesis of alkenes from tertiary esters utilizing the triphenylphosphine-iodine system |
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| Authors: | EJ Alvarez-Manzaneda R Chahboun E Alvarez A Haidour |
| Institution: | a Departamento de Química Orgánica, Facultad de Ciencias e Instituto de Biotecnología, Universidad de Granada, 18071 Granada, Spain b Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Almería, 04120 Almería, Spain |
| Abstract: | The treatment of tertiary esters with triphenylphosphine and iodine under mild conditions gives the most stable alkene in good yield. Formates, acetates and trifluoroacetates were studied. |
| Keywords: | Tertiary esters Elimination Alkenes Triphenylphosphine Iodine |
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