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Tetracyanoethylene oxide not only oxidizes sulfides to sulfoxides but also reduces sulfoxides to sulfides |
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| Authors: | Juzo Nakayama Ayako Tai Sachiko Iwasa Tomohiro Furuya Yoshiaki Sugihara |
| Affiliation: | Department of Chemistry, Faculty of Science, Saitama University, Saitama, Saitama 338-8570, Japan |
| Abstract: | It was found that tetracyanoethylene oxide not only oxidizes sulfides to sulfoxides but also reduces sulfoxides to sulfides with generation of two molecules of carbonyl cyanide. The reaction thus also functions as a new method for generation of carbonyl cyanide. |
| Keywords: | Oxidation and reduction Sulfur ylide Carbonyl cyanide Sulfide Sulfoxide |
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