Use of CaH2 as a reductive hydride source: reduction of ketones and imines with CaH2/ZnX2 in the presence of a Lewis acid |
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| Authors: | Toshio Aida |
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| Institution: | Department of Applied Chemistry, Kanagawa University, 3-27-1 Rokkakubashi, Kanagawa-ku, Yokohama 221-8686, Japan |
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| Abstract: | A new combination reagent of CaH2/ZnX2 effectively reduced a variety of ketones and imines to the corresponding alcohols and amines, respectively, in the presence of a catalytic amount of a Lewis acid such as Ti(O-i-Pr)4, Al(O-i-Pr)3, B(O-i-Pr)3 and ZnF2. |
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| Keywords: | Calcium hydride Reduction |
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