Selective palladium-catalyzed arylation(s) of benzaldehyde derivatives by N-heterocarbene ligands |
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Authors: | Nevin Gürbüz Bekir Çetinkaya |
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Institution: | a Inönü University, Department of Chemistry, 44069 Malatya, Turkey b Ege University, Department of Chemistry, 35100 Bornova-Izmir, Turkey |
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Abstract: | The 2- or 2,6-position(s) of aromatic aldehydes were directly and selectively arylated with aryl chlorides or bromides in the presence of a catalytic system prepared in situ from Pd(OAc)2, imidazolinium chlorides (1-5) and Cs2CO3. |
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Keywords: | C-H activation Arylations Pd-catalysis Aldehydes |
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