Mass spectrometry of π-complexes of transition metals. Communication 32. Derivatives of π-cyclopentadienyl-π-(3)-1,2-dicarbollyliron(III) |
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Authors: | N I Vasyukova D V Zagorevskii V V Kobak A I Kovredov L I Zakharkin |
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Institution: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions The basic paths have been established in the fragmentation of derivatives of -cyclopentadienyl- -(3)-1,2-dicarbollyliron(III) under electron impact: cleavage of the carbollyl-Fe bond, deep dehydrogenation, dehydration, and dehydrohalogenation. The carbollyl complexes are less stable to electron impact thatn are the ferrocene derivatives. In the molecular ions, the Cp-Fe bond is stronger than the carbollyl-Fe bond.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2246–2251, October, 1984. |
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