Development of a concise and diversity-oriented approach for the synthesis of plecomacrolides via the diene-ene RCM |
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| Authors: | Lu Kui Huang Mengwei Xiang Zheng Liu Yongxiang Chen Jiahua Yang Zhen |
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| Affiliation: | Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Beijing, China. |
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| Abstract: | [reaction: see text] A concise synthesis of the core structures of plecomacrolide with ring sizes varying from 16 to 19 atoms was achieved for the first time by the diene-ene ring-closing olefin metathesis reaction. This approach should allow access to the structurally diverse analogues of plecomacrolide. |
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