Quasilocalization of extra electrons in high density methane and ethane gases |
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Authors: | Norman Gee Gordon R. Freeman |
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Affiliation: | Chemistry Department, University of Alberta, Edmonton, Canada T6G 2G2 |
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Abstract: | The extent of electron quasilocalization in the high density gases is greater in ethane than in methane. However, the density required for quasilocalization in methane is n/nc > 0.1, while that in ethane is n/nc > 0.4, where nc is the critical density. The mobilities in methane and ethane cross at n = 6 × 1021 molecules/cm3, in the respective fluids along their vapor/liquid coexistence curves. |
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