Shell cross-linked Au nanoparticles |
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Authors: | Koenig Stéphanie Chechik Victor |
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Institution: | Department of Chemistry, University of York, Heslington, York YO10 5DD, UK. |
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Abstract: | The organic layer of thiol-protected Au nanoparticles (ca.3 nm in diameter) was cross-linked using ring-opening metathesis polymerization or Michael addition of polyfunctional amines. The shell cross-linked nanoparticles showed increased stability toward thermal treatment and oxidative etching. The Au core of cross-linked nanoparticles was removed in an attempt to prepare hollow capsules. However, Au etching resulted in insoluble materials. |
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