A new complex of Mn(II) with highly flexible bistriazole ligand 1,2-bis(1,2,4-triazole-l-yl)ethane: Synthesis and crystal structure |
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| Authors: | X X Wu B Ding R N Chang H A Zou Z Z Zhu |
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| Institution: | 1.Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry,Tianjin Normal University,Tianjin,PR. China |
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| Abstract: | Using a highly flexible ligand 1,2-bis(1,2,4-triazole-1-yl)ethane (L), the one-dimensional (1D) chain polymer Mn(L)(Cl)2(H2O)2] n (I) has been synthesized and structurally characterized. The crystal crystallizes in the monoclinic system, space group C2/c, a = 12.507(4), b = 8.812(3), c = 12.662(4) Å, β = 115.474(6)°, Z = 4. The X-ray analysis shows that I has the three-dimensional (3D) supramolecular network featuring 1D channel along the crystallographic y axis via intermolecular O-H...N interactions. |
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