Cycloaddition of diazocycloalkanes to [60]fullerene in the presence of Pd-containing complex catalyst |
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Authors: | A R Tuktarov V V Korolev A R Tulyabaev V M Yanybin L M Khalilov U M Dzhemilev |
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Institution: | 1.Institute of Petrochemistry and Catalysis,Russian Academy of Sciences,Ufa, Bashkortostan,Russian Federation |
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Abstract: | A catalytic method for the selective and efficient synthesis of cycloalkylidenehomofullerenes by cycloaddition of 60]fullerene
to diazocycloalkanes generated in situ from the corresponding hydrazones in the presence of a complex catalytic system Pd(acac)2-PPh3-Et3Al] has been developed. |
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