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Polyfuryl(aryl)alkanes and their derivatives. 2. Trifurylalkanes and mechanism of their formation
Authors:V. G. Kul'nevich  L. A. Solonenko  S. V. Zhuravlev
Affiliation:(1) Krasnodar Polytechnic Institute, 350006 Krasnodar
Abstract:Alkylfurans react with carboxylic acid anhydrides and chlorides in benzene in the presence of catalytic amounts of perchloric acid to give trifurylalkanes. The mechanism of the reaction, which is a consecutive process with the successive formation of an acylfuran, an alkyldifurylcarbinol, and a trifurylalkane, is examined. Intermediates, including an alkyldifurylcarbonium perchlorate, were isolated and characterized.See [1] for Communication 1.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 592–596, May, 1983.
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