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A new method for the synthesis of CF3-containing aminovinyl ketones
Authors:Krasovsky  A L  Nenajdenko  V G  Balenkova  E S
Institution:(1) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation
Abstract:A new method for the synthesis of aminovinyl trifluoromethyl ketones was developed. The method is based on the reactions of 4-sulfonyl-1,1,1-trifluorobut-3-ene-2,2-diols with various alkyl-, aryl-, dialkyl-, and alkylarylamines. The stereochemistry of the compounds obtained was studied.
Keywords:beta-sulfonylvinyl(trifluoromethyl)methanediols" target="_blank">gif" alt="beta" align="MIDDLE" BORDER="0">-sulfonylvinyl(trifluoromethyl)methanediols  amines  beta-trifluoroacetylvinylamines" target="_blank">gif" alt="beta" align="MIDDLE" BORDER="0">-trifluoroacetylvinylamines  enamines  stereochemistry  nucleophilic substitution
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