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A generic procedure for determining atomic LS spectral terms and their LS eigenfunctions
Authors:Xiong Zhuang and Bacalis  N C
Institution:AMS Research Center, Southeast University, Nanjing 210096, China; Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, Vasileos Constantinou 48, GR-11635 Athens, Greece
Abstract:This paper develops a Fortran code which is capable to construct the simplest LS eigenfunctions for desired symmetry and determine all permitted atomic LS spectral terms under a given orbital occupancy by implementing and extending the Schaefer and Harris method. Examples (in some cases the most complete set to date) of multiple spectroscopic terms of LS coupling of atomic states for both non-equivalent and equivalent electronic configurations are given. It also corrects a few observed errors from the recent literature.
Keywords:LS coupling  multiples  spectroscopic term
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